Gmail, the world's biggest e-mail service, has been largely inaccessible from within China since the run-up to the 25th anniversary in June of the Tiananmen Square crackdown on pro-democracy demonstrators.
But users could still access the service by using third-party mail applications, rather than the webpage.
"But they have blocked those ways of accessing," said Jeremy Goldkorn, founder of Danwei, a Beijing-based firm that tracks Chinese media and the Internet.
"I think this is pretty confirmed. It is now already four, five days, so this is real," he said.
Analysts say China operates the world's most extensive and sophisticated Internet censorship system and routinely blocks foreign websites.
"The past two years have seen a consistent tightening of all kinds of censorship on the Internet and media."
A graph showing Internet traffic from China accessing Gmail dropped sharply on Friday, according to Google's Transparency Report, and has not returned to normal levels.
"We've checked and there's nothing wrong on our end," a Singapore-based spokesman for Google told AFP.
The United States, while careful not to accuse Beijing directly, said it was aware of reports that Gmail had been blocked and that it was "concerned by efforts in China to undermine freedom of expression".
"We believe Chinese authorities' censorship of the media and of certain websites is... incompatible with China's aspirations to build a modern information-based economy and society," State Department spokesman Jeffrey Rathke said Monday.
"So we encourage China to be transparent in its dealings with international companies and to consider the market signal it sends with - with such acts," he added.
Internet users in China were irate Monday, with many spewing vitriol on Sina Weibo, a Twitter-like microblogging service.
"The reason for blocking of Gmail domestically is political problems... it reflects the grim situation facing the political environment," one user said.
Another commentator fumed, "Protest the government blocking Gmail! Demand its restoration!"
China tightly controls the Internet, and only a fraction of its online population of 632 million can circumvent government restrictions.
Controls include the blocking of foreign websites such as Facebook, Twitter and YouTube using a system known as the "Great Firewall", as well as routinely deleting content that the ruling Communist Party deems offensive.
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